Brandon doesn't really want sex. As a sex addict, he uses sex to comfort himself when his mind is distressed. What he really wants and needs, is a real human connection with another person. (The lack of that in his environment is what causes his mind to be distressed.) He was hoping to get that connection with the female coworker. She was rather shy and cute in the workplace and in the restaurant, seemingly real "girl-friend material". Instead of casual sex, he was after a meaningful relationship with her, seeking a human interaction where he could show his vulnerable self and get his doubts and problems off his chest.
But in the hotel room, he realizes either
- that she isn't really like that, she just likes him because of his status and regards him as a "score", she (like other women) wants him just for casual sex; or
- that she is different from the other women he's met, but that his behavior and treatment of her is corrupting her into the mindset of conquests and casual, meaningless sex.
Either way, he doesn't like where it's going, so he breaks it off. (Of course this causes distress in his mind, because he doesn't understand what he's been doing wrong and why he again doesn't get what he really wants; so next he needs something to ease his mind and therefore he hires a prostitute.)
At least that's my interpretation of the scene and his character.
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