One of the very first, episode #5. Unknowingly, Fred Flintstone drinks Barney's car polish, thinking that it's a Cactus Cooler soda (like in the later soda!), then finds out from Barney the truth, while miraculously not being harmed by it, freaks understandably so that he throws the bottles on himself, resulting in a doctor played by the barber in Andy Griffith (Howard MacNear, RIP 1904-1969) to come in with his absentminded diagnosis but then proves that he's a vet, followed by Wilma waking Fred up, and that's when he becomes in a semi-amnesiac state "Frederick"!! LOL
Betty to Barney:"WHY can't YOU be MORE like FREDERICK?"
Barney:(simmering..and somewhat sotto voce, aka low volume):"Frederick, Frederick"(David Seville like "Alvin" crescendo) Fredeick I HATE FREDERICK!!!"
LOLOLOLOL
"The Split Personality', 1960, 60-61 season, S1E5.
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It's available on Warner Home video since early 2000s.
I have the first four volumes.
Amanda Bynes is hot and Lindsay Lohan is not.
"Jewish People driving German cars"-Sarah Silverman.
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