Audrey is talking to some other girl in a bedroom and the girl tells her she's going away and asked Audrey to go with her? Maybe it's her sister or friend?
Thanks in advance!
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No, but if it's been many years since you have seen it, you may be confusing some things. That has happened to me several times with films that I'd seen long ago.
-- In the OPENING scene, she is in her bedroom packing to go to the convent. In the hallway, she talks to one of her sisters who doesn't want her to go.
-- NEAR THE END, she is talking with a young nurse, who is planning to enter the convent. She tells the nurse (Lisl, I think), that she is planning to leave the order, but is very encouraging to Lisl about her potential life as a nun.
This is probably the film that you are recalling. I can't think of another Audrey Hepburn film with a scene closer to the one that you described.
There's another scene less near the end where Lisa, the same young nurse, tells Sister Luke that she's going away from the hospital to her duties for the Underground. Even though she's not supposed to get involved, Sister Luke says to call on her if they need any help.
There's also a scene near the beginning where that pretty red-headed postulant (Patricia Bosworth) tells Sister Luke that she's bailing, she can't take it.
Then there's The Trouble With Angels, where Hayley Mills is staying in the convent and June Harding is heartbroken and refuses to believe it was her decision and has a very hard time leaving the convent school without her.
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Might you be thinking of the Children's Hour? Audrey and Shirley McLaine briefly discuss leaving and going to another place to start over again, but Shirley knows that will not solve the "problem."
When you described the scene you remember, that is the one that popped into my head.
Near the beginning of the film, Audrey and another Sister in her group break the Grand Silence, by talking on duty. The second Sister says that the Grand Silence doesn't concern her anymore, because she's leaving in the morning.
She then apologizes to "Sister Luke" for earning her another penance by talking with her...saying "I always start it". I think the girl is "Simone", the daughter of a man that "Sister Luke's" father had operated on. We first see them in the Convent parlor, before they say good bye to the outside world.