L'année dernière à Marienbad Modern Times Die Kinder vom Bahnhof Zoo 28 days later (yes, I really mean that) Citizen Kane The Brothers Grimm Apocalypse Now Nosferatu Vidocq Un chien andalou
Edit: Although morally more than questionable, consider the complete work of Leni Riefenstahl.
Suspiria (Argento) All That Heaven Allows (Sirk) Amelie Picnic at Hanging Rock (Weir) Onibaba The Conformist The Company of Wolves Fanny and Alexander (Bergman) Paris, Texas (Wenders) Juliet of the Spirits + Satyricon (Fellini)
I could second a lot already mentioned. Instead I will add a few movies that I have been tempted to mute and/or pause and just enjoy visually.
What Dreams May Come (1998) -- very very lush and beautiful Fantasia (1940)
Jesus of Nazareth (1977) -- directed by Franco Zeffirelli, see it on a decent color display
A Midsummer's Night Dream (1935) -- black and white, but goes as far as one can go. Won an Oscar for the lighting, the ONLY Oscar ever given to a write-in candidate. (By the way, Hitler hated it and banned it from Germany.) On a clear screen, the special effects and lighting is magical.
Gattacca (1997)
Sleeping Beauty (1959) -- Disney V for Vendetta (2005) Batman (1989) ... What these three have in common is that they have bright colors, visually engaging, but although that's like comic books (like that Dick Tracy (1990) movie), they use the colors masterfully to produce some gorgeous art ... one would like to have a large print of a frame on the wall. Sleeping Beauty uses an incredibly flavorful palatte.